What is the change in Gibbs free energy (ΔG) for the melting of three moles of water at 0°C?
1. | Zero | 2. | Positive |
3. | Negative | 4. | Unpredictable |
Assertion (A): | Decrease in free energy causes a spontaneous reaction. |
Reason (R): | Spontaneous reactions are invariably exothermic reactions. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Statement I: | \(\left(X_{\mathrm{m}}\right) \) is the value of an extensive property \(\left(X_{\mathrm{}}\right)\) of the system for 0.1 mol of the substance. | A molar property
Statement II: | \(X_{\mathrm{m}}=\chi / \mathrm{n}\) is independent of the amount of matter. | If n is the amount of matter,
1. | Statement I is correct; Statement II is correct |
2. | Statement I is incorrect; Statement II is incorrect |
3. | Statement I is correct; Statement II is incorrect |
4. | Statement I is incorrect; Statement II is correct |
Assertion (A): | Heat and work are "definite quantities". |
Reason (R): | Heat and work are not properties of a system their values depend on the path of the process and vary accordingly. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
In which of the following case, does the entropy decrease?
1. Boiling of egg
2. Combustion of benzene at 27oC
3. Combustion of benzene at 127oC
4. Dissolution of sugar in water
1. | \(\Delta H\) | 2. | \(\Delta S_{Total}\) |
3. | \(\Delta S_{System}\) | 4. | \(\Delta G^o\) |
Statement I: | Total enthalpy change of a multistep process is the sum of ∆H1 + ∆H2 + ∆H3 + . . . |
Statement II: | When heat is absorbed by the system, the sign of q is taken to be negative. |
1. | Statement I is correct; Statement II is correct. |
2. | Statement I is correct; Statement II is incorrect. |
3. | Statement I is incorrect; Statement II is correct. |
4. | Statement I is incorrect; Statement II is incorrect. |
Based on the reactions, ascertain the valid algebraic relationship:
1. | x = y | 2. | x = 2y |
3. | x > y | 4. | x < y |
Assertion (A): | The heat absorbed during the isothermal expansion of an ideal gas against a vacuum is zero. |
Reason (R): | The volume occupied by the molecules of an ideal gas is zero. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Assertion (A): | Enthalpy and entropy of any elementary substance in the standard states are taken as zero. |
Reason (R): | At absolute zero, particles of the perfectly crystalline substance become completely motionless. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |