At 1990 K and 1 atm pressure, there are an equal number of Cl2 molecules and Cl atoms in the reaction mixture.
The value of KP for the reaction under the above conditions is x × 10–1. The value of x is:
1. 4
2. 8
3. 5
4. 10
For the reaction A(g)(B)(g), the value of the equilibrium constant at 300 K and 1 atm is equal to 100.0. The value of rG for the reaction at 300 K and 1 atm in J mol–1 is – xR, where x is:
(R = 8.31 J mol–1 K–1 and ln 10 = 2.3)
1. 1400
2. 1380
3. 1360
4. 1340
For a reaction; , 1.0 mol of X, 1.5 mol of Y and 0.5 mol of Z were taken in a 1 L vessel and allowed to react. At equilibrium, the concentration of Z was 1.0 mol L–1 . The equilibrium constant of the reaction is . The value of x is:
1. 24
2. 13
3. 16
4. 19
Given that the equilibrium constant KC at 800 K for the reaction N2(𝑔)+3H2(𝑔)⇋2NH3(𝑔) is 64. What is the equilibrium constant KC at 800 K for the given-below reaction is:
NH3(g) ⇌ 1/2N2(g) + 3/2H2(g)
1. | \(\dfrac{1}{4}\) | 2. | \(\dfrac{1}{8}\) |
3. | 8 | 4. | \(\dfrac{1}{64}\) |
For the following reactions, equilibrium constants are given below:
S(s) + O2(g) SO2(g); K1 = 1052
2S(s) + 3O2(g) 2SO3(g); K2 = 10129
The equilibrium constant for the reaction, 2SO2(g) + O2(g) 2SO3(g) is:
1. | 10154 | 2. | 10181 |
3. | 1025 | 4. | 1077 |
The equilibrium constant at 298 K for a reaction A + B ⇋ C + D is 100.
If the initial concentration of all the four species were 1 M each,
then equilibrium concentration of D (in mol L–1) will be :
1. | 0.182 | 2. | 0.818 |
3. | 1.818 | 4. | 1.182 |
A vessel at 1000 K contains CO2 with a pressure of 0.5 atm. Some of the CO2 is converted into CO on the addition of graphite. If the total pressure at equilibrium is 0.8 atm, the value of K is :
1. 1.8 atm
2. 3 atm
3. 0.3 atm
4. 0.18 atm
In a closed reaction vessel, Phosphorus pentachloride dissociates as follows:
\(\mathrm{PCl}_{5}(g) \rightleftharpoons \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g)\)
If the total pressure at equilibrium of the reaction mixture is P and the degree of dissociation of PCl5 is x, the partial pressure of PCl3 will be:
1. \(\left(\frac{x}{x+1}\right) P\)
2. \(\left(\frac{2x}{x-1}\right) P\)
3. \(\left(\frac{x}{x-1}\right) P\)
4. \(\left(\frac{x}{1-x}\right) P\)
Consider the reaction equilibrium : \(2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g) ; \quad \Delta H^{\circ}=-198 \mathrm{~kJ} \)
On the basis of Le-Chatelier's principle, the condition favorable for the forward reaction is :
1. lowering of temperature as well as pressure
2. increasing temperature as well as pressure
3. lowering the temperature and increasing the pressure
4. Any value of temperature and pressure
For the reaction equilibrium, \(\mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_2(g) \), the concentrations of N2O4 and NO2 at equilibrium are 4.8 \(\times\) 10-2 and 1.2 \(\times\) 10-2 mol L-1 respectively. The value of Kc for the reaction is:
1. 3.3 \(\times\) 102 mol L-1
2. 3 \(\times\) 10-1 mol L-1
3. 3 \(\times\) 10-3 mol L-1
4. 3 \(\times\) 103 mol L-1