| Statement I: | Like nitrogen that can form ammonia, arsenic can form arsine. | 
| Statement II: | Antimony cannot form antimony pentoxide. | 
| 1. | Statement I is correct but Statement II is incorrect | 
| 2. | Statement I is incorrect but Statement II is correct | 
| 3. | Both Statement I and Statement II are correct | 
| 4. | Both Statement I and Statement II are incorrect | 
| 1. | Se | 2. | Te | 
| 3. | Po | 4. | O | 
| Statement I: | The boiling point of hydrides of Group 16 elements follow the order \(\text{H}_2 \text{O}>\text{H}_2 \text{Te}>\text{H}_2 \text{Se}>\text{H}_2 \text{S} .\) | 
| Statement II: | On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. | 
| 1. | \(\mathrm{PCl_5}\) possesses two different \(\mathrm{Cl-P-Cl}\) bond angles. | 
| 2. | All five \(\mathrm{P-Cl}\) bonds are identical in length. | 
| 3. | \(\mathrm{PCl_5}\) exhibits sp3d hybridisation. | 
| 4. | \(\mathrm{PCl_5}\) consists of five \(\mathrm{P-Cl}\) (sigma) bonds. | 
| 1. | The acidic strength of HX (X=F, Cl, Br and I) follows the order: HF > HCI > HBr >HI | 
| 2. | Fluorine exhibits - 1 oxidation state whereas other halogens exhibit +1, +3, +5 and +7 oxidation states also. | 
| 3. | The enthalpy of dissociation of F2 is smaller than that of Cl2. | 
| 4. | Fluorine is stronger oxidising agent than chlorine. | 
| 1. | \(\mathrm{PEt}_3\) and \(\mathrm{Asph}_3\) as ligands can form \(\mathrm{d} \pi-\mathrm{d} \pi\) bond with transition metals. | 
| 2. | The \(\mathrm{N}-\mathrm{N}\) single bond is as strong as the \(\mathrm{P}-\mathrm{P}\) single bond. | 
| 3. | Nitrogen has unique ability to form \(\mathrm{p \pi-p \pi}\) multiple bonds with nitrogen, carbon and oxygen. | 
| 4. | Nitrogen cannot form \(\mathrm{d} \pi-\mathrm{p} \pi\) bond as other heavier elements of its group. | 
| List-I (Oxoacids of Sulphur) | List-II (Bonds) | ||
| A. | Peroxodisulphuric acid | I. | Two S-OH, Four S=O, One S-O-S | 
| B. | Sulphuric acid | II. | Two S-OH, One S=O | 
| C. | Pyrosulphuric acid | III. | Two S-OH, Four S=O, One S-O-O-S | 
| D. | Sulphurous acid | IV. | Two S-OH, Two S=O | 
| Options: | A | B | C | D | 
| 1. | III | IV | II | I | 
| 2. | I | III | II | IV | 
| 3. | III | IV | I | II | 
| 4. | I | III | IV | II | 
| Assertion (A): | ICl is more reactive than I₂. | 
| Reason (R): | I-Cl bond is weaker than I-I bond. | 
| 1. | (A) is False but (R) is True. | 
| 2. | Both (A) and (R) are True and (R) is the correct explanation of (A). | 
| 3. | Both (A) and (R) are True but (R) is not the correct explanation of (A). | 
| 4. | (A) is True but (R) is False. | 
| Statement I: | The boiling points of the following hydrides of group 16 elements increase in the order \(\mathrm{H}_{2} \mathrm{O}<\mathrm{H}_{2} \mathrm{~S}<\mathrm{H}_{2} \mathrm{Se}<\mathrm{H}_{2} \mathrm{Te} \) | 
| Statement II: | The boiling points of these hydrides increase with the increase in molar mass. | 
The correct order for boiling points of the following compounds is:
| 1. | AsH3 > PH3 > NH3 > SbH3 > BiH3 | 
| 2. | BiH3 > SbH3 > NH3 > AsH3 > PH3 | 
| 3. | NH3 > PH3 > AsH3 > SbH3 > BiH3 | 
| 4. | PH3 > NH3 > AsH3 > SbH3 > BiH3 |