The oxidation states of the central atom in the given species are, respectively:

${\mathrm{H}}_4{\mathrm{P}}_2{\mathrm{O}}_7$  $\mathrm{and}$ ${\mathrm{H}}_2{\mathrm{S}}_2{\mathrm{O}}_7$

KI₃, H₂S₄O₆

The oxidation numbers of iodine and sulphur in the above compounds are, respectively:

1. $\dfrac{1}{3}$ ; 4
2. 2.5 ; $\dfrac{1}{3}$
3. $-\dfrac{1}{3}$ ; 2.5
4. 2.5 ; 3

Which of the following reactions does not involve disproportionation process?

1. ${\mathrm{Cl}}_2+{\mathrm{OH}}^{-}\to {\mathrm{Cl}}^{-}+{\mathrm{ClO}}_3^{-}+{\mathrm{H}}_2\mathrm{O}$

2. $2{\mathrm{H}}_2{\mathrm{O}}_2\to {\mathrm{H}}_2\mathrm{O}+{\mathrm{O}}_2$

3. $2{\mathrm{Cu}}^{+}\to {\mathrm{Cu}}^{2+}+\mathrm{Cu}$

4. ${\left({\mathrm{NH}}_4\right)}_{2}C{r}_2{O}_7\to {\mathrm{N}}_2+{\mathrm{Cr}}_2{\mathrm{O}}_3+4{\mathrm{H}}_2\mathrm{O}$

Which of the following reactions does not represent a redox change?

1. CaCO₃ $\to$CaO + CO₂

2. 2H₂ + O₂ $\to$2H₂O

3. Na + H₂O $\to$ NaOH + $\frac{1}{2}$H₂

4. MnCl₃ $\to$ MnCl₂ + $\frac{1}{2}$Cl₂

Fluorine reacts with ice as per the following reaction

H₂O(s) + F₂(g) → HF(g) + HOF(g)

This reaction is a redox reaction because-

The formulas for the following compounds are: 

(a) Mercury(II) chloride  and (b) Thallium(I) sulphate

1. HgCl₂,  Tl₂SO₄

2. Hg₂Cl₂, Tl₂SO₄

3. HgCl₂,  TlSO₄

4. HgCl₂,  Tl₃SO₄

In the given balanced chemical reaction

$\mathrm{IO}_3^{-}+\mathrm{aI}^{-}+\mathrm{bH}^{+} \rightarrow \mathrm{cH}_2 \mathrm{O}+\mathrm{dI}_2$

The values of a, b, c, and d respectively are:

1. 5, 6, 3, 3

2. 5, 3, 6, 3

3. 3, 5, 3, 6

4. 5, 6, 5, 5

The balanced equation for the reaction between chlorine and sulphur dioxide in water is:

For the redox reaction,
 a${\mathrm{MnO}}_4^{-}+{\mathrm{bC}}_2{\mathrm{O}}_4^{2-}+{\mathrm{cH}}^{+}\to {\mathrm{dMn}}^{2+}+{\mathrm{eCO}}_2+{\mathrm{fH}}_2\mathrm{O}$
the correct stoichiometric coefficients of the reactants a, b, and c respectively for the balanced equation are: 

1. 16, 5, 2
2. 2, 5, 16
3. 2, 16, 5
4. 5, 16, 2