Match the reagents from List-I with the corresponding radicals from List-II and choose the correct option:
List-I
(Reagent)
List-II
(Radical)
(i)  \(\text { dil. } \mathrm{HCl}\) (A)  \(\mathrm{Pb}^{2+}\)
(ii)  \(\begin{aligned} & \mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH}+ \\ & \left(\mathrm{NH}_4\right)_2 \mathrm{CO}_3 \end{aligned}\) (B)  \(\mathrm{Al}^{3+}\)
(iii)  \(\mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH}+\mathrm{H}_2 \mathrm{~S}\) (C)  \(\mathrm{Mn}^{2+}\)
(iv)  \(\mathrm{NH}_4 \mathrm{Cl}+\mathrm{NH}_4 \mathrm{OH}\) (D)  \(\mathrm{Sr}^{2+}\)
 
1. (i)-(A), (ii)-(D), (iii)-(C), (iv)-(B)
2. (i)-(D), (ii)-(A), (iii)-(C), (iv)-(B)
3. (i)-(A), (ii)-(D), (iii)-(B), (iv)-(C)
4. (i)-(B), (ii)-(C), (iii)-(D), (iv)-(A)
Subtopic:  Detection of Cations |
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Which of the following cations will turn a borax bead green when heated in a reducing (luminous) flame?

1. \(\mathrm{Fe^{3+}}\) 2. \(\mathrm{Cu^{2+}}\)
3. \(\mathrm{Mn^{2+}}\) 4. \(\mathrm{Ni^{2+}}\)
Subtopic:  Detection of Cations |
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Match the tests in List-I with their corresponding identification in List-II:
List-I (Test) List-II (Identification)
(i)  Baeyer’s test (p)  Aldehyde
(ii)  Ceric ammonium nitrate test (q)  Alcohol
(iii)  Phthalein dye test (r)  Phenol
(iv)  Schiff’s test (s)  Unsaturation

1. i → (p), ii → (q), iii → (r), iv → (s)
2. i → (s), ii → (q), iii → (r), iv → (p)
3. i → (s), ii → (q), iii → (p), iv → (r)
4. i → (q), ii → (s), iii → (r), iv → (p)
Subtopic:  Detection of the functional groups |
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Match the anion radicals given in List I with the corresponding characteristics in List II and select the correct option given below:
List-I (Anions) List-II
(Gas evolved on reaction with dil H2SO4)
A. \(\mathrm{CO}_3^{2-}\) I. Colourless gas that turns lead acetate paper black.
B. \(\mathrm{S}^{2-}\) II. Colourless gas that turns acidified potassium dichromate solution green.
C. \(\mathrm{SO}_3^{2-}\) III. Brown fumes that turn acidified \(\mathrm{KI}\) solution containing starch blue.
D. \(\mathrm{NO}_2^{-}\) IV. Colourless gas evolved with brisk effervescence, which turns lime water milky.
Codes:

1. A-III, B-I, C-II, D-IV
2. A-II, B-I, C-IV, D-III
3. A-IV, B-I, C-III, D-II
4. A-IV, B-I, C-II, D-III
Subtopic:  Detection of Anions |
 77%
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Identify the inorganic sulphides that are yellow in colour:
(A) (NH4)2S
(B) PbS
(C) CuS
(D) As2S3
(E) As2S5
Choose the correct answer from the options given below :
1. (A) and (C) only
2. (A), (D) and (E) only
3. (A) and (B) only
4. (D) and (E) only
Subtopic:  Detection of Cations |
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Identify A, B and C in the given below reaction sequence:

1. PbCl2 , PbSO4 , PbCrO4
2. PbS, PbSO4 , PbCrO4
3. PbS, PbSO4 , Pb(CH3COO)2
4. PbCl2 , Pb(SO4)2 , PbCrO4
Subtopic:  Detection of Cations |
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