Select the correct option based on statements below:
Assertion (A): | The rate constant determined from the Arrhenius equation is fairly accurate for simple as well as complex molecules. |
Reason (R): | Reactant molecules undergo chemical change irrespective of their orientation during a collision. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Select the correct option based on statements below:
Assertion (A): | All collisions of reactant molecules lead to product formation. |
Reason (R): | Only those collisions in which molecules have the correct orientation and sufficient kinetic energy lead to the compound formation. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | The enthalpy of reaction remains constant in the presence of a catalyst. |
Reason (R): | A catalyst participating in the reaction forms a different activated complex and lowers down the activation energy but the difference in energy of the reactant and the product remains the same. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Order and molecularity are the same. |
Reason (R): | Order is determined experimentally, and molecularity is the sum of the stoichiometric coefficient of the rate-determining the elementary step. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | The order of the reaction can be zero or fractional. |
Reason (R): | We cannot determine order from the balanced chemical equation. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Select the correct option based on statements below:
Assertion (A): | The overall order of reaction is the sum of the power of all the reactants in the rate expression. |
Reason (R): | There are many higher-order reactions. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
Assertion (A): | Base catalyzed hydrolysis of ethyl acetate is a first-order reversible reaction. |
Reason (R): | The order of reaction always depends on the stoichiometry of the reaction. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
Assertion (A): | At very high temperatures (approaches to infinity), the rate constant becomes equal to the collision frequency. |
Reason (R): | The collision in which molecules collide with proper orientation is called an ineffective collision. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
Select the correct option based on statements below:
Assertion (A): | For elementary reactions, the law of mass action and the rate of law expression are generally the same. |
Reason (R): | The molecularity of an elementary reaction is always one. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | Both (A) and (R) are false. |
For the reaction, 2A → B, rates= k[A]2. If the concentration of reactant is doubled, then the:
(a) | rate of reaction will be doubled. |
(b) | rate constant will remain unchanged, however rate of reaction is directly proportional to the rate constant. |
(c) | rate constant will change since the rate of reaction and rate constant are directly proportional to each other. |
(d) | rate of reaction will increase by four times. |
Identify the set of correct statements & choose the correct answer from the options given below:
1. | (a) and (c) only | 2. | (a) and (b) only |
3. | (b) and (d) only | 4. | (c) and (d) only |