What is the name of the below mentioned reaction?
\(\small{\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{OH}+\mathrm{CH}_3 \mathrm{COCl} \stackrel{\text { Pyridine }}{\longrightarrow} \mathrm{CH}_3 \mathrm{COOC}_2 \mathrm{H}_5+\mathrm{HCl}}\)
1. Acetylation
2. Cannizzaro reaction
3. Cross aldol condensation
4. Decarboxylation
The reaction that does not give benzoic acid as the major product is:
1. | \(\xrightarrow{K_2Cr_2O_7}\) | 2. | \(\xrightarrow[(ii)H_3O^+]{(i)NaOCl}\) |
3. | \(\xrightarrow{PCC}\) | 4. | \(\xrightarrow{KMnO_4/H^+}\) |
An acid that forms an anhydride (X) on heating and an acid imide (Y) on strong heating with ammonia is:
1. | 2. | ||
3. | 4. |
Select the correct option based on statements below:
Assertion (A): | Aldehydes and ketones both react with Tollen’s reagent to form a silver mirror. |
Reason (R): | Both aldehydes and ketones contain a carbonyl group. |
1. | Both (A) and (R) are true and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are true but (R) is not the correct explanation of (A). |
3. | (A) is true but (R) is false. |
4. | (A) is false but (R) is true. |
Select the correct option based on statements below:
Assertion (A): | Aromatic aldehydes and formaldehydes undergo the Cannizzaro reaction. |
Reason (R): | Aromatic aldehydes are almost as reactive as formaldehyde. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | The α -hydrogen atom in carbonyl compounds is less acidic. |
Reason (R): | The anion formed after the loss of the α -hydrogen atom is resonance stabilized. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on statements below:
Assertion (A): | Compounds containing —CHO group are easily oxidised to corresponding carboxylic acids. |
Reason (R): | Carboxylic acids can be reduced to alcohol by treatment with LiAlH4. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | (A) is False but (R) is True. |
Select the correct option based on the statements below:
Assertion (A): | The geometry of formaldehyde molecule is planar. |
Reason (R): | Formaldehyde molecule contains sp2 hybridized carbon atom. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Match the example in Column I with the name of the reaction in Column II.
Column l (Example) |
Column ll (Reaction) |
A. | 1. Friedel-Crafts acylation |
B. | 2. HVZ reaction |
C. | 3. Aldol condensation |
D. | 4. Rosenmund Reaction |
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 1 | 4 | 2 |
3. | 3 | 4 | 1 | 2 |
4. | 4 | 1 | 3 | 2 |
Match the reactions given in Column I with the suitable reagents given in Column II.
Column l (Reactions) |
Column ll (Reagents) |
A. Benzophenone → Diphenylmethane | 1. LiAlH4 |
B. Benzaldehyde → 1-Phenylethanol | 2. DlBAL-H |
C. Cyclohexanone → Cyclohexanol | 3. Zn(Hg)/Conc.HCl |
D. Phenyl benzoate → Benzaldehyde | 4. CH3MgBr |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 3 | 4 | 1 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 3 | 2 | 1 |