Which one of the following reactions does not come under hydrolysis type reaction?
1. \(\mathrm{S i C l_{4 \left(\right. l \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow S i O_{2 \left(\right. s \left.\right)} + 4 H C l_{\left(\right. a q \left.\right)}}\)
2. \(\mathrm{L i_{3} N_{\left(\right. s \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow N H_{3 \left(\right. g \left.\right)} + 3 L i O H_{\left(\right. a q \left.\right)}}\)
3. \(\mathrm{2 F_{2 \left(\right. g \left.\right)} + 2 H_{2} O_{\left(\right. l \left.\right)} \rightarrow 4 H F_{\left(\right. a q \left.\right)} + O_{2 \left(\right. g \left.\right)}}\)
4. \(\mathrm{P_{4} O_{10 \left(\right. s \left.\right)} + 6 H_{2} O_{\left(\right. l \left.\right)} \rightarrow 4 H_{3} P O_{4 \left(\right. a q \left.\right)}}\)
The given sequence among the following arrangements that is not strictly according to the property indicated against it.
1. | \(\small{\text{increasing} \ p K_{a}\ \text{values}}\) | H2O < H2S < H2Se < H2Te :
2. | \(\small{\mathrm{N H_{3} < P H_{3} < A s H_{3} < S b H_{3}} : \text{increasing acidic character}}\) |
3. | \(\small{\mathrm{C O_{} < S i O_{} < S n O_{} < P b O_{2}} : \text{increasing oxidising power}} \) |
4. | \(\small{\mathrm{H F < H C l < H B r < H I} : \text{increasing acidic strength}} \) |
Match List-I (substances) with List-II (processes) employed in the manufacture of the substances and select the correct option.
List –I (Substances) | List – II (Processes) |
(a) Sulphuric acid | (i) Haber's Process |
(b) Steel | (ii) Bessemer's Process |
(c) Sodium carbonate | (iii) Leblanc Process |
(d) Ammonia | (iv) Contact Process |
Options : | (a) | (b) | (c) | (d) |
1. | (i) | (ii) | (iii) | (iv) |
2. | (iv) | (iii) | (ii) | (i) |
3. | (iv) | (ii) | (iii) | (i) |
4. | (i) | (iv) | (ii) | (iii) |
Wrong statement among the following is:
1. Bond energy of F2 > Cl2
2. Electronegativity of F > Cl
3. F is more oxidizing than Cl
4. Electron affinity of Cl > F
From the given options, the compound that has a planar structure is:
1. XeF4
2. XeOF2
3. XeO2F2
4. XeO4
Oxidation number of P in pyrophosphoric acid is:
1. +5
2. +2
3. +3
4. +4
A compound having two direct bonds between P and H atoms is:
1.
2.
3.
4.
General behavior of is:
1. To give electrons
2. To Give
3. Reaction with
4. To accept electrons
The correct statement among the following is:
1. | Silicon exhibits 8 coordination numbers in its compound. |
2. | The bond energy of F2 is less than Cl2. |
3. | Mn(III) oxidation state is more stable than Mn (II) in an aqueous state. |
4. | Elements of 15th gp show only + 3 and + 5 oxidation states. |
Incorrect statement among the following is:
1. | Among halide ions, iodide is the most powerful reducing agent. |
2. | Fluorine is the only halogen that does not show a variable oxidation state. |
3. | HOCl is a stronger acid than HOBr |
4. | HF is a stronger acid than HCl |