The correct graphical representation of first-order reaction is:
(a) | (b) | ||
(c) | (d) |
1. | (a) and (b) | 2. | (b) and (c) |
3. | (c) and (d) | 4. | (a) and (d) |
Column I | Column II | ||
A. | Catalyst alters the rate of reaction | 1. | Proper orientation is not there always |
B. | 2. | By lowering the activation energy | |
C. | Energetically favorable reactions are sometimes slow | 3. | Total probability is one |
D. | Area under the Maxwell-Boltzmann curve is constant | 4. | Refers to the fraction of molecules with energy equal to or greater than the activation energy |
Codes:
A | B | C | D | |
1. | 2 | 4 | 1 | 3 |
2. | 3 | 1 | 4 | 2 |
3. | 1 | 4 | 3 | 2 |
4. | 3 | 4 | 1 | 2 |
Select the correct option based on statements below:
Assertion (A): | The enthalpy of reaction remains constant in the presence of a catalyst. |
Reason (R): | A catalyst participating in the reaction forms a different activated complex and lowers down the activation energy but the difference in energy of the reactant and the product remains the same. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Consider the first-order gas-phase decomposition reaction given below.
A(g) → B(g) + C(g)
The initial pressure of the system before the decomposition of A was . After the lapse of time t, the total pressure of the system increased by X units and became . The rate constant k for the reaction is:
1. | 2. | ||
3. | 4. |
For a first-order reaction A → B the reaction rate at a reactant concentration of 0.01M is found to be . The half-life period of the reaction is:
1. | 300s | 2. | 30s |
3. | 220s | 4. | 347s |
The decomposition of N2O5 in CCl4 at 318K has been studied by monitoring the concentration of N2O5 in the solution. Initially, the concentration of N2O5 is 2.33 mol L–1 and after 184 minutes, it is reduced to 2.08 mol L–1. The reaction takes place according to the equation
2 N2O5 (g) → 4 NO2 (g) + O2 (g)
The rate of production of NO2 during this period is-
1. 5.72 × 10–3 mol L–1 min–1
2. 2.72 × 10–3 mol L–1 min–1
3. 1.72 × 10–5 mol L–1 min–1
4. 6.72 × 10–4 mol L–1 min–1
In a first order reaction, time required for completion of 99.9% is X times of half-life (t1/2) of the reaction. When reaction is completed 99.9%, [R]n = [R]0 – 0.999[R]0 .The value of X is-
1. 5
2. 10
3. 15
4. 20
If 75 % of a first-order reaction was completed in 90 minutes, 60 % of the same reaction would be completed in approximately (in minutes):
(Take : log 2 = 0.30 ; log 2.5 = 0.40)
1. 50 min
2. 60 min
3. 70 min
4. 65 min
The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ ) of the reaction is:
(Take R=8.314 J In 3.555=1.268)
1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol
For the non – stoichiometry reaction 2A + B → C + D, the following kinetic data were obtained in three separate experiments (all at 298 K).
Initial Concentration (A) | Initial Concentration (B) | Initial rate of formation of C (mol L– S–) |
0.1 M 0.1 M 0.2 M |
0.1 M 0.2 M 0.1 M |
1.2 × 10–3 1.2 × 10–3 2.4 × 10–3 |
The rate law for the formation of C is:
1.
2.
3.
4.