Consider the following data:
Λ°m(Ca2+) = 119.0 S cm2mol–1
Λ°m(Cl-) = 76.3 S cm2mol–1
Λ°m(Mg2+) = 106.0 S cm2mol–1
Λ°m(\(SO_{4}^{2-}\)) = 160.0 S cm2mol–1
The correct statement among the following is-
1. | For CaCl2 Λ°m is 271.6 S cm2 mol–1 and for MgSO4 Λ°m is 266 S cm2 mol–1. |
2. | For CaCl2 Λ°m is 195.3 S cm2 mol–1 and for MgSO4 Λ°m is 266 S cm2 mol–1. |
3. | For CaCl2 Λ°m is 271.6 S cm2 mol–1 and for MgSO4 Λ°m is 133 S cm2 mol–1. |
4. | For CaCl2 Λ°m is 135.8 S cm2 mol–1 and for MgSO4 Λ°m is 133 S cm2 mol–1. |
Λ°m for NaCl, HCl and NaAc are 126.4, 425.9 and 91.0 S cm2 mol–1 respectively. The value of Λ°m for HAc is-
1. | 380.9 S cm2 mol–1 | 2. | 390.5 S cm2 mol–1 |
3. | 400 S cm2 mol–1 | 4. | 410.6 S cm2 mol–1 |
The conductivity of 0.001028 mol L–1 acetic acid is 4.95 ×10–5 S cm–1. if Λ°m for acetic acid is 390.5 S cm2 mol–1, Its dissociation constant value is-
1. 1.58 × 10–5 mol L–1
2. 1.78 × 10–5 mol L–1
3. 1.98 × 10–5 mol L–1
4. 2.18 × 10–5 mol L–1