When a copper wire is immersed in a solution of AgNO3, the colour of the solution becomes blue because copper:

1. Forms a soluble complex with \(AgNO_3\)
2. Is oxidised to \(Cu^{2+}\)
3. Is reduced to \(Cu^{2-}\)
4. Splits up into atomic form and dissolves

Subtopic:  Electrochemical Series |
 80%
Level 1: 80%+
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The voltage of the cell given below increases with: 

Cell: Sn(s) + 2Ag+(aq) → Sn2+(aq) + 2Ag(s)

1. Increase in size of the silver rod.

2. Increase in the concentration of Sn2+ ions.

3. Increase in the concentration of Ag+ ions.

4. None of the above.

Subtopic:  Nernst Equation |
 63%
Level 2: 60%+
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The standard electrode potential for Sn4+/Sn2+ couple is +0.15 V and that for the Cr3+/Cr couple is -0.74 V. These two couples in their standard state are connected to make a cell. The cell potential will be: 

1. +0.89 V 2. +0.18 V
3. +1.83 V 4. +1.199 V
Subtopic:  Electrode & Electrode Potential |
 91%
Level 1: 80%+
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If an iron rod is dipped in CuSO4 solution, then:

1. Blue colour of the solution turns red.

2. Brown layer is deposited on iron rod.

3. No change occurs in the colour of the solution.

4. None of the above.

Subtopic:  Electrochemical Series |
Level 3: 35%-60%
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Without losing it's concentration, ZnCl2 solution cannot be kept in contact with :

1. Au

2. Al

3. Pb

4. Ag

Subtopic:  Electrochemical Series |
 74%
Level 2: 60%+
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The standard reduction potential for Fe2+|Fe and Sn2+|Sn electrodes are -0.44 V and -0.14 V respectively. For the cell reaction,

Fe2+ + Sn   Fe + Sn2+, the standard Emf is - 

1. +0.30 V

2. 0.58 V

3. +0.58 V

4. -0.30 V

Subtopic:  Electrode & Electrode Potential |
 64%
Level 2: 60%+
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Three Faradays of electrical charge are passed consecutively through four separate electrolytic cells containing aqueous solutions of AgNO3, CuSO4, Al(NO3)3, and NaCl. What will be the molar ratio of the respective metals deposited at each cathode?

1. 1 : 2 : 3 : 1 2. 6 : 3 : 2 : 6
3. 6 : 3 : 0 : 0 4. 3 : 2 : 1 : 0
Subtopic:  Faraday’s Law of Electrolysis |
Level 4: Below 35%
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The standard reduction electrode potentials of three metals X, Y, and Z are given as -1.2 V, +0.5 V, and -3.0 V, respectively. Based on these values, what is the correct order of their reducing power?

1. Y > X >Z 2. Z > X > Y
3. X > Y > Z 4. Y > Z > X
Subtopic:  Electrochemical Series |
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A solution containing one mole per litre each of Cu(NO3)2, AgNO3, Hg2(NO3)2 and Mg(NO3)2 is being electrolyzed by using inert electrodes. The values of standard electrode potentials in volt (reduction potentials) are,

Ag/Ag = 0.80 V, Hg22+/2Hg = 0.79 V,

Cu2+/Cu = +0.34 V and Mg2+/Mg = -2.37 V

With increasing voltage, the sequence of deposition of metals on the cathode will be:

1. Ag, Hg, Cu, Mg

2. Mg, Cu, Hg, Ag

3. Ag, Hg, Cu

4. Cu, Hg, Ag

Subtopic:  Electrochemical Series |
Level 3: 35%-60%
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The change in reduction potential of a hydrogen electrode when its solution initialy at pH = 0 is neutralised to pH = 7, is a/an-

1. Increase by 0.059 V 2. Decrease by 0.059 V
3. Increase by 0.41 V 4. Decrease by 0.41 V
Subtopic:  Electrode & Electrode Potential | Nernst Equation |
 55%
Level 3: 35%-60%
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