Consider the following relations for emf of an electrochemical cell:

(a)	emf of a cell = (Oxidation potential of the anode) – (Reduction potential of the cathode)
(b)	emf of a cell = (Oxidation potential of the anode) + (Reduction potential of the cathode)
(c)	emf of a cell = (Reduction potential of the anode) + (Reduction potential of the cathode)
(d)	emf of a cell = (Oxidation potential of the anode) – (Oxidation potential of the cathode)

Which of the following combinations correctly represents the relation for the emf of the cell?

1.	(a) and (b)	2.	(c) and (d)
3.	(b) and (d)	4.	(c) and (a)

The correct expression that  represents the equivalent conductance at infinite dilution of $A{l}_2{\left(S{O}_4\right)}_3$ is:

(Given that ${\wedge }_{A{l}^{3+}}^{°}$ $and$ ${\wedge }_{S{O}_4^{2-}}^{°}$ are the equivalent conductances at infinite dilution of the respective ions)

1. ${\wedge }_{A{l}^{3+}}^{°}$ $+$ ${\wedge }_{S{O}_4^{2-}}^{°}$

2. $\left({\wedge }_{A{l}^{3+}}^{°}\right)$ $+$ ${\wedge }_{S{O}_4^{2-}}^{°}\times 6$

3. $\frac{1}{3}{\wedge }_{A{l}^{3+}}^{°}$ $+\frac{1}{2}$ ${\wedge }_{S{O}_4^{2-}}^{°}$

4. $2{\wedge }_{A{l}^{3+}}^{°}$ $+3$ ${\wedge }_{S{O}_4^{2-}}^{°}$

Molar conductivities $(\wedge {°}_m)$ at infinite dilution of
NaCl, HCl, and $C{H}_{3}COONa$ are 126.4, 425.9, and 91.0 S cm² mol^–1 respectively.
 $(\wedge {°}_m)$  for $C{H}_{3}COOH$  will be: 

The Gibb's energy for the decomposition of \(\mathrm{A l_{2} O_{3}}\) at \(\mathrm{500~ ^\circ C}\) is as follows: 

2/3Al₂O₃ → 4/3Al + O₂ ; ∆_rG = + 960 k J mol^–1

The potential difference needed for the electrolytic reduction of aluminium oxide (Al₂O₃) at \(\mathrm{500~ ^\circ C}\) is at least,

1. 3.0 V 

2. 2.5 V 

3. 5.0 V 

4. 4.5 V 

${\mathrm{}}^{}$What is the mass of silver deposited when the charge passed is doubled, if a charge of \(10^5\) coulomb deposits 1 g of Ag?

The concentration of $ZnC{l}_2$ solution will change when it is placed in a container which is made of:

Which of the following quantities does the change in Gibbs free energy (ΔG) depend upon, for the electrochemical cell reaction: \(Cu^{2+}(C_{1}) + Zn \to Cu + Zn^{2+}(C_{2})\)

\(1. \ ln (C_{1}+C_{2})\)
2. \(ln (\frac{C_{2}}{C_{1}})\)
\(3. \ ln C_{2}\)
\(4. \ lnC_{1}\)

4.5 g of aluminium (at. mass = 27 amu) is deposited at cathode from Al³⁺ solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from H⁺ ions in solution by the same quantity of electric charge will be:

For the disproportionation of copper:

2Cu⁺ → C u²⁺ + C u$,$ $E°$ is:
(Given $E°$ for Cu⁺²/Cu is 0.34 V & Eº for Cu⁺²/Cu⁺ is 0.15 V )

1. 0.49 V

2. – 0.19 V

3. 0.38 V

4. – 0.38 V

A cell reaction become spontaneous when:

1. ∆Gº is negative

2. ∆Gº is positive

3. $E_{Red}^{°}$ is positive

4. $E_{Red}^{°}$ is negative