Consider the following relations for emf of an electrochemical cell:

(a) emf of a cell = (Oxidation potential of the anode) – (Reduction potential of the cathode)
(b) emf of a cell = (Oxidation potential of the anode) + (Reduction potential of the cathode)
(c) emf of a cell = (Reduction potential of the anode) + (Reduction potential of the cathode)
(d) emf of a cell = (Oxidation potential of the anode) – (Oxidation potential of the cathode)


Which of the following combinations correctly represents the relation for the emf of the cell?

1. (a) and (b) 2. (c) and (d)
3. (b) and (d) 4. (c) and (a)

Subtopic:  Electrode & Electrode Potential |
 70%
Level 2: 60%+
AIPMT - 2010
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Molar conductivities (°m) at infinite dilution of
NaCl, HCl, and CH3COONa are 126.4, 425.9, and 91.0 S cm2 mol–1 respectively.
 (°m)  for CH3COOH  will be: 

1. \(180.5~S~cm^2~mol^{-1}\) 2. \(290.8~S~cm^2~mol^{-1}\)
3. \(390.5~S~cm^2~mol^{-1}\) 4. \(425.5~S~cm^2~mol^{-1}\)
Subtopic:   Kohlrausch Law & Cell Constant |
 91%
Level 1: 80%+
AIPMT - 2012
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Given the standard electrode potentials:

K+/K = –2.93 V
Ag+/Ag = 0.80 V
Hg2+/Hg = 0.79 V
Mg2+/Mg = –2.37 V
Cr3+/Cr = – 0.74 V
The correct increasing order of reducing power of the metals is:  
1. Cr < Mg < K < Ag < Hg 2. Mg < K < Ag < Hg < Cr
3. K < Ag < Hg < Cr < Mg 4. Ag < Hg < Cr < Mg < K
Subtopic:  Electrode & Electrode Potential |
 86%
Level 1: 80%+
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The correct statement about the given galvanic cell equation is:

Zn(s) + 2Ag+­­­(aq) → Zn2+(aq) + 2Ag(s)

1. The current will flow from silver to zinc in the external circuit.
2. The current will flow from zinc to silver in the external circuit.
3. The current will flow from silver to zinc in the internal circuit.
4. The current will flow from zinc to silver in the internal circuit.

Subtopic:  Electrolytic & Electrochemical Cell |
 64%
Level 2: 60%+
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 2Cr(s) + 3Cd2+(aq)  2Cr3+(aq) + 3Cd

ECr3+/Cr= -0.74 VECd2+/Cd=-0.40 V

The value of Gro in the above reaction will be-

1. -196.83 kJ

2. 196.83 kJ

3. 186.83 kJ

4. -186.83 kJ

Subtopic:  Relation between Emf, G, Kc & pH |
 78%
Level 2: 60%+
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The incorrect statement(s) among the following is/are:

(a) The unit of conductivity is S cm–2.
(b) Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration.
(c) The unit of molar conductivity is S cm2 mol–1.
(d) Molar conductivity increases with an increase in concentration.


1. Only (a)

2. (a) and (d)

3. (b) and (d)

4. (a) and (c)

Subtopic:  Conductance & Conductivity |
 57%
Level 3: 35%-60%
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The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1. The molar conductivity will be -

1. 124 S cm2 mol-1 2. 134 S cm2 mol-1
3. 128 S cm2 mol-1 4. 136 S cm2 mol-1
Subtopic:  Conductance & Conductivity |
 90%
Level 1: 80%+
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The electricity required in coulombs for the oxidation of 1 mole of FeO to \(Fe_{2} O_{3 }\) is:

1. 964.87 C 2. 96487 C
3. 96.487 C 4. 9.6487 C
Subtopic:  Faraday’s Law of Electrolysis |
 88%
Level 1: 80%+
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\(Fe^{2+}(aq) \ + \ Ag^{+}(aq) \ \rightarrow \ Fe^{3+}(aq) \ + \ Ag(s)\)

\(E_{Fe^{3+}/Fe^{2+}}^{o} \ = \ 0.77 \ V; \ E_{Ag^{+}/Ag}^{o} \ = \ 0.80 \ V\)

The value of \(\Delta G_{r}^{o} \)  in 
the above reaction will be:

1. +2.89 kJ

2. -2.89 kJ

3. -2.89 J

4. -186.83 J

Subtopic:  Relation between Emf, G, Kc & pH |
 83%
Level 1: 80%+
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The value of Ecell in the reaction below will be:

\(\small{Pt(s)|Br^{-}(0.010 \ M)|Br_{2}(l) \ ||H^{+}(0.030 \ M)|H_{2}(g)(1 \ bar)|Pt(s)}\)

\(E_{Br^{-}/Br_{2}}^{o} \ = \ -1.09 \ V\)

1. +1.298 V

2. –1.398 V

3. –1.298 V

4. –1.198 V
Subtopic:  Nernst Equation |
Level 3: 35%-60%
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