The azeotropic mixture of water and ethanol boils at 78.15 oC. When this mixture is distilled, it is possible to obtain-
1. Pure H2O
2. Pure C2H5OH
3. Pure H2O as well as pure C2HOH
4. Neither H2O nor C2H5OH in their pure state
Preservation of fruits against bacterial action by adding sugar is an example of-
1. Exosmosis
2. Reverse-osmosis
3. Diffusion
4. Capillary action
The freezing point of depression constant (Kf ) of benzene is 5.12 K kg mol–1. The freezing point depression for the solution of molality 0.078 m containing a non-electrolyte solute in benzene is:
(rounded off up to two decimal places)
1. 0.80 K
2. 0.40 K
3. 0.60 K
4. 0.20 K
Colligative properties depend on:
1. | The nature of the solute particles dissolved in the solution. |
2. | The number of solute particles in the solution. |
3. | The physical properties of the solute particles dissolved in the solution. |
4. | The nature of solvent particles. |
A solution that has the highest boiling point among the following is:
1. 1.0 M NaOH
2. 1.0 M Na2SO4
3. 1.0 M NH4NO3
4. 1.0 M KNO3
The unit of Ebullioscopic constant is:
1. K kg mol–1 or K (molality)–1
2. mol kg K–1 or K–1 (molality)
3. kg mol–1 K–1 or K–1 (molality)–1
4. K mol kg–1 or K (molality)
In comparison to a 0.01 M solution of glucose, the depression in the freezing point of a 0.01 M MgCl2 solution will be:
1. | Same | 2. | About twice |
3. | About three times | 4. | About six times |
Match the laws given in Column I with expressions given in Column II.
Column I | Column II |
A. Raoult’s law | 1. = CRT |
B. Osmotic pressure | 2. |
C. Elevation of boiling point | 3. |
D. Depression in freezing point | 4. |
Codes
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 1 | 2 | 3 | 4 |
3. | 1 | 4 | 3 | 2 |
4. | 3 | 1 | 4 | 2 |
The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol individually. The mixture shows:
1. No deviation from Raoult's law
2. Positive deviation from Raoult's law
3. Negative deviation from Raoult's law
4. That the solution is unsaturated
A pair of isotonic solutions, among the following, is (assuming temperature to be the same) :
1. 0.1 (M) urea and 0.1 (M) NaCl
2. 0.1 (M) urea and 0.2 (M) MgCl2
3. 0.1 (M) NaCl and 0.1 (M) Na2SO4
4. 0.1 (M) Ca(NO3)2 and 0.1 (M) Na2SO4