i. | ii. | ||
iii. | iv. | ||
v | vi | ||
vii |
1. | 5 | 2. | 4 |
3. | 6 | 4. | 2 |
1. | (a) > (c) > (e) > (d) > (b) | 2. | (c) > (d) > (a) > (e) > (b) |
3. | (a) > (e) > (b) > (c) > (d) | 4. | (a) > (e) > (c) > (b) > (d) |
The compound obtained by addition of water to an alkyne having more than two carbons, in the presence of \(\mathrm{HgSO_4 }\) and dilute \(\mathrm{H_2SO_4}\) at 333K, is:
1. A vicinal diol
2. An aldehyde
3. An alcohol
4. A ketone
Match the bond line structures of hydrocarbons given in List I with the corresponding boiling points given in List II.
List-I (Compound) | List II (Boiling point in K) | ||
(a) | (i) | 300.9 | |
(b) | (ii) | 282.5 | |
(c) | (iii) | 309.1 | |
(d) | (iv) | 341.9 |
(a) | (b) | (c) | (d) | |
1. | (i) | (iv) | (iii) | (ii) |
2. | (iii) | (i) | (iv) | (ii) |
3. | (iii) | (iv) | (i) | (ii) |
4. | (iv) | (i) | (ii) | (iii) |
1. | 2. | ||
3. | 4. |
Statement I : | The boiling point of three isomeric pentanes follows the order \(\text { n-Pentane }>\text { Isopentane }>\text { Neopentane }\) |
Statement II : | When branching increases, the molecule attains the shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. |
1. | 2. | ||
3. | 4. |