Consider the following reaction:
2A (g) + B (g) → 2D (g)
\(ΔU^⊖\)=−10 \(kJ mol^{−1}\) and \(ΔS^⊖\)=−44 \(J K^{−1}\) at 298 K.

Identify the correct option with \(ΔG^⊖\) for the reaction and spontaneity of the reaction at 298 K.
(Given : R=\(8.31 ~J mol^{−1} K^{−1}\))
1. −1.635 kJ mol−1, spontaneous
2. +0.63568 kJ mol−1, non-spontaneous
3. −0.63568 kJ mol−1, spontaneous
4. +1.635 kJ mol−1, non-spontaneous
Subtopic:  Spontaneity & Entropy | Gibbs Energy Change |
 56%
Level 3: 35%-60%
NEET - 2026
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Two moles of an ideal gas undergo free expansion from 10 L to 100 L at 300 K. The Values of \(\Delta \mathrm{S}_{\text {system }}\) and \(\Delta \mathrm{S}_{\text {surroundings }}\) are :
(R is  universal gas constant)
 
1. \(\Delta \mathrm{S}_{\text {system }}=4.606 \mathrm~{R} ; \Delta \mathrm{S}_{\text {surroundings }}=0\)
2. \(\Delta \mathrm{~S}_{\text {system }}=0 ;~ \Delta \mathrm{S}_{\text {surroundings }}=0 \)
3. \(\Delta \mathrm{~S}_{\text {system }}=4.606~ \mathrm{R} ; \Delta \mathrm{S}_{\text {surroundings }}= -4.606 \mathrm{R}\)
4. \(\Delta \mathrm{~S}_{\text {system }}=0 ; \quad \Delta ~~\mathrm{S}_{\text {surroundings }}= 4.606 \mathrm{R}\)
Subtopic:  Spontaneity & Entropy |
Level 4: Below 35%
NEET - 2026
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In which of the following processes entropy increases?
A. A liquid evaporates to vapour.
B. Temperature of a crystalline solid lowered from \(130~\text{K}\) to \(0~\text{K}.\)
C. \(2 \mathrm{NaHCO}_{3(\mathrm{~s})} \rightarrow \mathrm{Na}_2 \mathrm{CO}_{3(\mathrm{~s})}+\mathrm{CO}_{2(\mathrm{~g})}+\mathrm{H}_2 \mathrm{O}_{(\mathrm{g})}\)
D. \(\mathrm{Cl}_{2(\mathrm{~g})} \rightarrow 2 \mathrm{Cl}_{(\mathrm{g})}\)
Choose the correct answer from the options given below:
1. \(\text { A, B and D }\) 2. \(\text { A, C and D }\)
3. \(\text { C and D }\) 4. \(\text { A and C }\)
Subtopic:  Spontaneity & Entropy |
 73%
Level 2: 60%+
NEET - 2024
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Which of the following statements is correct for an irreversible isothermal expansion of an ideal gas?

1. U=0,Stotal0

2. U0,Stotal=0

3. U=0,Stotal=0

4. U0,Stotal0

Subtopic:  Spontaneity & Entropy |
 69%
Level 2: 60%+
NEET - 2021
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For the reaction, 2Cl(g)  Cl2(g), the correct option is:
1. \(\Delta_{\mathrm{r}} \mathrm{H}>0\) and \(\Delta_{\mathrm{r}} \mathrm{S}<0 \) 2. \(\Delta_{\mathrm{r}} \mathrm{H}<0\) and \( \Delta_{\mathrm{r}} \mathrm{S}>0 \)
3. \(\Delta_{\mathrm{r}} \mathrm{H}<0 \) and \(\Delta_{\mathrm{r}} \mathrm{S}<0 \) 4. \(\Delta_{\mathrm{r}} \mathrm{H}>0\) and \( \Delta_{\mathrm{r}} \mathrm{S}>0\)
Subtopic:  Enthalpy & Internal energy | Spontaneity & Entropy |
 61%
Level 2: 60%+
NEET - 2020
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If for a certain reaction rH is 30 kJ mol–1 at 450 K, the value of rS (in JK–1 mol–1) for which the same reaction will be spontaneous at the same temperature is:

1. 70 2. –33
3. 33 4. –70
Subtopic:  Spontaneity & Entropy |
 71%
Level 2: 60%+
NEET - 2020
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