Statement I: | The standard enthalpy change for the formation of one mole of a compound from its elements in their most stable states (reference states) is called standard molar enthalpy of formation. |
Statement II: | For, CaO(s)+ CO2 (g) → CaCO3(s) ; ∆fH⊝ = -178.3 kJmol-1 , the ∆rH⊝ is equal to the ∆fH⊝ . |
1. Both statements I and II are true.
2. Statement I is true; and statement II is false.
3. Both statements I and II are false.
4. Statement I is false; statement II is true.
Statement I: | Pressure, molar heat capacity, density, mole fraction, specific heat, temperature, and molarity are intensive properties. |
Statement II: | Mass, internal energy, and heat capacity are extensive properties. |
Assertion (A): | \(\Delta S_{system} > 0 \) as well as \(\Delta H > 0 \) passes from non-spontaneous to spontaneous state as temperature is increased. | A process for which
Reason (R): | \(T \Delta S \) exceeds \(\Delta H \). | At higher temperatures,
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | \(C_p - C_v = R \), for 1 mole of an ideal gas. |
Reason (R): | R is equal to the work done when the temperature of one mole of an ideal gas is increased by 1º. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | The temperature of a gas does not change when it undergoes an adiabatic expansion. |
Reason (R): | During an adiabatic process, the container should be a perfect conductor. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Heat energy is completely transformed into work during the isothermal expansion of a gas. |
Reason (R): | During an isothermal process, the changes in the internal energy of a gas due to a decrease in pressure are nullified by the changes due to an increase in volume. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | During an adiabatic process, heat energy is not exchanged between the system and its surroundings. |
Reason (R): | The temperature of a gas increases when it undergoes an adiabatic expansion. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |
Assertion (A): | Mass and volume are extensive properties. |
Reason (R): | Mass/volume is also an extensive property. |
1. | Both (A) and (R) are True and (R) is the correct explanation of (A). |
2. | Both (A) and (R) are True but (R) is not the correct explanation of (A). |
3. | (A) is True but (R) is False. |
4. | Both (A) and (R) are False. |