Consider the following statements 
a. In crystallization, an impure compound is dissolved in a solvent in which it is highly soluble at room temperature. 
b. In the positive resonance effect(+R), the transfer of electrons is always from an atom or substituted group attached to the conjugated system. 
c. One of the technological applications of fractional distillation is to separate different fractions of crude oil in the petroleum industry.
The correct statements are: 
1. (a) and (b) only  2. (b) and (c) only 
3. (a) and (c) only  4. (a), (b), and (c) 
Subtopic:  Electron Displacement Effects |
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The correct arrangement of the following carbocations in decreasing order of their stability is:



1. A > B > C > D
2. B > C > A > D
3. C > B > A > D
4. C > A > B > D
Subtopic:  Electron Displacement Effects |
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The hyperconjugation effect is not observed in: 
 
(i) (ii)       
(iii) (iv)

1. (i) and (ii)
2. (i), (ii) and (iii)
3. (i) only 
4. (i), (ii) and (iv) 
Subtopic:  Electron Displacement Effects |
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Consider the resonance structure of CH3COOCHas follows:



The correct statement among the following is-

1. I and II cannot be the major contributors to the real structure of CH3COOCH3
2. I and II can be the major contributors to the real structure of CH3COOCH3
3. I is more stable than II.
4. None of the above
Subtopic:  Electron Displacement Effects |
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The most stable carbanion, amongst the following is:
1. 2.
3. 4.
Subtopic:  Electron Displacement Effects | Reaction Intermediates ; Preparation & Properties |
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The correct order of decreasing stability of the following is:
\(\left(\mathrm{CH}_3\right)_3 \mathrm{C}^{-}, ^{-}\mathrm{CCl}_3,\left(\mathrm{CH}_3\right)_2 \mathrm{CH}^{-}, \mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2^{-}\)

1. \({ }^{-} \mathrm{CCl}_3>\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2^{-}>\left(\mathrm{CH}_3\right)_2 \mathrm{CH}^{-}>\left(\mathrm{CH}_3\right)_3 \mathrm{C}^{-} \)
2. \(\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2^{-}>{ }^{-} \mathrm{CCl}_3>\left(\mathrm{CH}_3\right)_2 \mathrm{CH}^{-}>\left(\mathrm{CH}_3\right)_3 \mathrm{C}^{-} \)
3. \(\mathrm{C}_6 \mathrm{H}_5-\mathrm{CH}_2^{-}>~^{-} \mathrm{CCl}_3>\left(\mathrm{CH}_3\right)_3 \mathrm{C}^{-}>\left(\mathrm{CH}_3\right)_2 \mathrm{CH}^{-} \)
4. None of the above

Subtopic:  Electron Displacement Effects |
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