For the reaction, the plot of log k vs is given below :
Find the temperature(K) at which the rate constant of the reaction is 10–4s–1 ?
(Rounded-off to the nearest integer)
[Given: The rate constant of the reaction is
1. | 546 K | 2. | 536 K |
3. | 516 K | 4. | 526 K |
The rate constant of a reaction increases by five times on increase in temperature from 27°C to 52°C. The value of activation energy in kJ mol–1 is-
(Rounded-off to the nearest integer) [R = 8.314 J K–1 mol–1]
1. 50
2. 56
3. 52
4. 60
The results given in the below table were obtained during kinetic studies of the following reaction:
2A + B C + D
Experiment | [A]/mol L-1 | [B]/mol L-1 | Initial rate/mol L-1 min-1 |
I | 0.1 | 0.1 | 6.0010-3 |
II | 0.1 | 0.2 | 2.4010-2 |
III | 0.2 | 0.1 | 1.2010-2 |
IV | X | 0.2 | 7.2010-2 |
V | 0.3 | Y | 2.8810-1 |
X and Y in the given table are respectively :
1. 0.3, 0.4
2. 0.4, 0.3
3. 0.4, 0.4
4. 0.3, 0.3
For the reaction , the correct statement is:
1. | |
2. | |
3. | |
4. |
If 75 % of a first-order reaction was completed in 90 minutes, 60 % of the same reaction would be completed in approximately (in minutes):
(Take : log 2 = 0.30 ; log 2.5 = 0.40)
1. 50 min
2. 60 min
3. 70 min
4. 65 min
The rate constant (k) of a reaction is measured at different temperatures (T), and the data are plotted in the given figure. The activation energy of the reaction in kJ mol–1 is:
(R is gas constant)
1. 2R
2. R
3. 1/R
4. 2/R
The rate of a reaction is decreased by 3.555 times when the temperature was changed from 40°C to 30°C. The activation energy (in kJ ) of the reaction is:
(Take R=8.314 J In 3.555=1.268)
1. 100 kJ/mol
2. 120 kJ/mol
3. 95 kJ/mol
4. 108 kJ/mol
For the reaction , the values of initial rate at different reactant concentrations are given in the table below. The rate law for the reaction is:
[A] (mol L-1) | [B] (mol L-1) | Initial Rate (mol L-1 s-1) |
0.05 | 0.05 | 0.045 |
0.10 | 0.05 | 0.090 |
0.20 | 0.10 | 0.72 |
1. Rate = k[A] [B]
2. Rate = k [A]
3. Rate =
4. Rate =