Which aryl halide is most reactive towards aromatic nucleophilic substitution reaction?

1. 2.
3. 4.
Subtopic:  Chemical Properties | Haloarenes: Directive Influence of Halogen |
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Given below are two statements: 

Assertion (A): It is difficult to replace chlorine by -OH in chlorobenzene in comparison to that in chloroethane.
Reason (R): Chlorine carbon (C—Cl) bond in chlorobenzene has a partial double bond character due to resonance.

 

1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.

Subtopic:  Chemical Properties | Haloarenes: Directive Influence of Halogen |
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Which of the following is the halogen exchange reaction?

1. R X + NaI \(\xrightarrow{\text{ Acetone }}\) RI + NaX
2.
3. R - OH + HX \(\xrightarrow{\text{ ZnCl}_2~~}\) R - X + H2O
4.

Subtopic:  Chemical Properties | Haloarenes: Directive Influence of Halogen |
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The reaction of toluene with chlorine in the presence of iron and in the absence of light produces:

1.
2.
3.
4. Mixture of 2 and 3
Subtopic:  Haloarenes: Directive Influence of Halogen |
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Arrange the compounds in increasing order of rate of reaction towards nucleophilic substitution.

 

1.  (i) < (ii) < (iii) 

2.  (ii) < (i) < (iii) 

3.  (iii) < (ii) < (i) 

4.  (i) < (iii) < (ii) 

Subtopic:  Haloarenes: Directive Influence of Halogen |
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Level 1: 80%+

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