Aluminium becomes passive in nitric acid because it-
1. Is a noble metal
2. Forms a thin film of oxide
3. Has a positive reduction potential
4. None of the above
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The stability of the +1 oxidation state increases in the sequence:
1. Al <Ga<In<Tl
2. Tl<In<Ga<Al
3. In<Tl<Ga<Al
4. Ga<In<Al<Tl
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\(\mathrm{Al}_2 \mathrm{O}_3\) reacts with-
1. | Only water | 2. | Only acids |
3. | Only alkalis | 4. | Both acids and alkalis |
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The correct explanation for the lower atomic radius of Ga as compared to Al is -
1. Poor shielding effect of the 2d-electrons
2. Poor shielding effect of the 3d-electrons
3. Poor shielding effect of the 3p-electrons
4. Poor shielding effect of the 2s-electrons
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Borax bead test is responded by:
1. Divalent metals
2. Heavy metals
3. Light metals
4. Metal which forms coloured metaborates
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Match the species given in Column I with the properties mentioned in Column II.
Column I | Column II |
A. \(\text{BF}^-_4\) | 1. Oxidation state of the central atom is +4 |
B. AlCl3 | 2. Tetrahedral shape |
C. SnO | 3. Lewis acid |
D. PbO2 | 4. Can be further oxidized |
Codes:
A | B | C | D | |
1. | 2 | 3 | 4 | 1 |
2. | 1 | 2 | 3 | 4 |
3. | 1 | 4 | 3 | 2 |
4. | 4 | 1 | 3 | 2 |
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The products formed by the oxidation of are:
1.
2.
3.
4.
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AlF3 is soluble in HF only in the presence of KF due to the formation of:
1. | K3[AlF3H3] | 2. | K3[AlF6] |
3. | AlH3 | 4. | K[AlF3H] |
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From the following, the compound(s) that react(s) with \(\mathrm{BF}_3\) is/are -
1. | Ethers | 2. | \( \mathrm{H}_2 \mathrm{O} \) |
3. | \(\mathrm{NH}_3 \) | 4. | All of the above |
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Aluminium chloride in acidified aqueous solution forms a complex 'A'.
The formula of A and hybridisation state of Al in 'A' is respectively:
1. [Al(H2O)6]3+, sp3d2
2. [Al(H2O)4]3+, sp3
3. [Al(H2O)4]3+, dsp2
4. [Al(H2O)]3+, d2sp3
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