The hybridization involved in the complex NiCN42-is:
(Atomic number of Ni=28)

1. dsp2

2. sp3

3. d2sp2

4. d2sp3

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An ion, among the following, that has a magnetic moment of 2.84 BM is:
(At. no. Ni = 28, Ti = 22, Cr = 24, Co = 27)

1. Ni2+
2. Ti3+
3. Cr2+
4. Co2+

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The correct statement, among the following, is:

1. [Co(CN)6]3- has no unpaired electrons and will be
in a low-spin configuration.
2. [Co(CN)6]3- has four unpaired electrons and will be
in a low-spin configuration.
3. [Co(CN)6]3- has four unpaired electrons and will be
In a high-spin configuration.
4. [Co(CN)6]3- has no unpaired electrons and will be
in a high-spin configuration.

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Among the following complexes the one which shows zero crystal field stabilization energy (CFSE) is:

1. [Ni(H2O)6]3+

2. [Fe(H2O)6]3+

3. [Co(H2O)6]2+

4. [Co(H2O)6]3+

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An ion that has magnetic moment 2.83 BM is:
(Atomic Number: Ti=22, Cr=24, Mn=25, Ni=28)

1. Ti3+

2. Ni2+

3. Cr3+

4. Mn2+

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A magnetic moment of 1.73 BM will be shown by which one of the following:
1. [Ni(CN)4]2–
2. TiCl4
3. [CoCl6]4–
4. [Cu(NH3)4]2+
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Crystal field splitting energy for high spin doctahedral complex is:
1. – 1.2 \(\Delta_{0}\)
2. – 0.6 \(\Delta_{0}\)
3. – 0.8 \(\Delta_{0}\)
4. –1.6 \(\Delta_{0}\)
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Which complex among the following exhibits a paramagnetic nature?

1. [Co(NH3)6]3+
2. [Pt(en)Cl2]
3. [CoBr4]2–
4. Mo(CO)6
(At. No. Mo = 42, Pt = 78)
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A diamagnetic compound among the following is:

1. [Co(F6)]3–
2. [Ni(CN)4]2–
3. [NiCl4]2–
4. [Fe(CN)6]3–
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Which one of the following is an outer orbital complex and exhibits paramagnetic behavior?

1. [Ni(NH3)6]2+

2. [Zn(NH3)6]2+

3. [Cr(NH3)6]3+

4. [Co(NH3)6]3+

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