The relationship between temperature and the variance in reaction rate is:

1.  2.
3. 4.
Subtopic:  Arrhenius Equation |
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The activation energy of one of the reactions in a biochemical process is \(\mathrm{532611~ J~ mol^{–1} .}\) When the temperature falls from \(\mathrm{310~ K}\) to \(\mathrm{300~ K,}\) the change in rate constant observed is \(\mathrm{k_{300} = x × 10^{–3} k_{310}.}\)
The value of \(\mathrm{x}\) is:
[Given: ln\(\mathrm{10 = 2.3, R = 8.3 ~JK^{–1} mol^{–1}}\) ]
1. 1 2. 5
3. 2 4. 8
Subtopic:  Arrhenius Equation |
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What is the pre-exponential factor for a reaction at 500 K with a rate constant of 0.02 s⁻¹ and an activation energy of 18.230 kJ?


1. 1.61
2. 1.41
3. 1.81
4. 1.21
Subtopic:  Arrhenius Equation |
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The activation energy for the reaction 2HI(g) → H2 + I2(g) is 209.5 kJ mol−1 at 581K.  The fraction of molecules of reactants having energy equal to or greater than activation energy is-

1. 2.67 × 10−19
2. 3.57 × 10−18
3. 4.67 × 10−17
4. 1.47 × 10−19
Subtopic:  Arrhenius Equation |
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Consider the given two statements:
Assertion(A): The active complex is an intermediate product.
Reason(R): The active complex is unstable because of high energy.
Select the correct option:
1. Both (A) and (R) are True and (R) is the correct explanation of (A).
2. Both (A) and (R) are True but (R) is not the correct explanation of (A).
3. (A) is True but (R) is False.
4. (A) is False but (R) is True.
 
Subtopic:  Arrhenius Equation |
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For reaction \(A \longrightarrow B,\) the rate constant \(k_1=A_1 e^{-E a_1 /(R T)}\) and
for the reaction \(X \longrightarrow Y \text {, }\)the rate constant \(k_2=A_2 e^{-E a_2 /(R T)}.\) 
If \(A_1=10^8, A_2=10^{10}\) and \(E_{a_1}=600~ \mathrm{cal} / \mathrm{mol},\) \(E_{a_2}=1800~ \mathrm{cal} / \mathrm{mol},\) 
then the temperature at which \(k_1=k_2\) is:\(\text { (Given : } R=2 \mathrm{cal} / \mathrm{K}-\mathrm{mol} \text { ) }\)
1. \(1200 \mathrm{~K}\) 2. \(1200 \times 4.606 \mathrm{~K}\)
3. \(\dfrac{1200}{4.606} \mathrm{~K}\) 4. \(\dfrac{600}{4.606} \mathrm{~K}\)
Subtopic:  Arrhenius Equation |
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