Statement I: | Benzendiazonium chloride is a colourless crystalline solid. It is insoluble in water but reacts with water when warmed. |
Statement II: | Benzendiazonium chloride on reacting with HCI in presence of copper powder gives chlorobenzene as the product. This is an example of Gatterman reaction. |
List-I (Reagent) |
List-II (name of the reaction) |
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A. | Carbylamine test | I. | Phenol |
B. | Bayer's test | II. | Acetone |
C. | Iodoform test | III. | Ethylene |
D. | Phthalein dye test | IV. | Aniline |
List-I (Amine) |
List-II \(\textbf{(pK}_{\beta} ~\textbf{value}) \) |
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A. | Benzenamine | I. | 3.38 |
B. | Phenylmethanamine | II. | 9.38 |
C. | Methenamine | III. | 4.70 |
D. | N-Ethylethanamine | IV. | 3.0 |
Statement I: | Aniline does not undergo Friedel-Crafts alkylation reaction. |
Statement II: | Aniline cannot be prepared through Gabriel synthesis. |
1. | Both Statement I and Statement II are incorrect. |
2. | Statement I is correct and Statement II is incorrect. |
3. | Statement I is incorrect and Statement II is correct. |
4. | Both Statement I and Statement II are correct. |
1. | 2. | ||
3. | 4. |
1. | 2. | ||
3. | 4. |
1. | |
2. | |
3. | |
4. |
Column - I (Reaction) |
Column - II (Product formed) |
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(a) | Gabriel synthesis | (i) | Benzaldehyde |
(b) | Kolbe synthesis | (ii) | Ethers |
(c) | Williamson synthesis | (iii) | Primary amines |
(d) | Etard reaction | (iv) | Salicylic acid |
(a) | (b) | (c) | (d) | |
1. | (iii) | (i) | (ii) | (iv) |
2. | (ii) | (iii) | (i) | (iv) |
3. | (iv) | (iii) | (i) | (ii) |
4. | (iii) | (iv) | (ii) | (i) |