Cations are present in the interstitial sites in ............ .

1.  Frenkel defect.

2.  Schottky defect.

3.  Vacancy defect.

4.  Metal deficiency defect.

 

HINT: There is no effect on density in case of Frenkel defect.
 
Explanation: When smaller ion (usually cation) is dislocated from its normal site in crystal and move to interstitial site is known as Frenkel defect as shown below: