I. Mg(s)

II. TiO(s)

III. I2(s)

IV. H2O(s)

The insulator among the given examples is -

1. Only I

2. Only II

3. III and IV

4. II, III, and IV

HINT: Molecular solids are insulators.
Explanation:
Iodine is a non-polar molecular solid in which iodine molecules are held together by London force or dispersion force. This is a soft and non-conductor of electricity.
Water is a hydrogen-bonded molecular solid in which H and O are held together by polar covalent bonds and each water molecule is held together by hydrogen bonding. Due to non-ionic nature, they are not an electrical conductor.