The electronic configuration of some elements is given in Column I and their electron gain enthalpies are given in Column II. Match the electronic configuration with the electron gain enthalpy.

Column I

(Electron configuration)

Column II

(Electron gain enthalpy/kJ mol–1)

A. 

1s22s22p6

(i).

–53

B. 

1s22s22p63s1

(ii).

–328

C. 

1s22s22p5

(iii).

–141

D. 

1s22s22p4

(iv).

+48

Codes:

Options:  A   B   C   D 
1.  (iv) (i) (ii) (iii)
2. (i) (ii) (iii) (iv)
3. (i) (iv) (iii) (ii)
4. (iv) (i) (iii) (ii)

 
A.(4) B.(1) C.(2) D.(3)
A. This electronic configuration corresponds to the noble gas i.e., neon. Since, noble gases have +egH values, therefore, electronic configuration (A) corresponds to the egH=+48kJmol-1.
B. This electronic configuration corresponds to the alkali metal i.e., potassium. Alkali metals have small negative egH values, hence, electronic configuration (B) correspongds to egH=-53kJmol-1.
C. This electronic configuration corresponds to the halogen i.e., fluorine. Since, halogens have high negative egH values, therefore, electronic configuration (C) corresponds to egH=328kJmol-1.
D. This electronic configuration corresponds to the chalcogen i.e., oxygen. Since, chalcogens have egH values less negative than those of halogens, therefore, electronic configuration (D) corresponds to egH=-141kJmol-1.